Proof: Suppose , with not all zero. Then, if we differentiate we obtain
and differentiate again, we obtain
Therefore, we have
Remark.
The converse is not true. The functions and are linearly independent but their Wronskian is 0 everywhere. So non-null Wronskian implies independence but null Wronskian DO NOT implies linear independence.
On the other hand, a converse can be proven by requiring stronger assumptions on , for example analyticity or if they are known to be the solutions of the same linear ODE of the form , where is a linear differential operator with respect to of order less than . See Wikipedia.