Derivation by Schrodinger (post-hoc rationalization)
Consider old quantum theory, and let's focus on the case of a free particle. Probably, the reasoning of Erwin was as follows:
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It seems that particles have an associated wave, whose parameters are given by the Einstein (
) and De Broglie ( ) relations, according to the experiments. Let's call this wave . The oscillation/vibration takes place in a kind of internal space. -
If the "internal space" were
, then the associated wave might be . What PDE is satisfied by this function? A key observation was that $$-\frac{\hbar^2}{2m} \nabla^2 (\Psi)=\frac{p^2}{2m}\Psi$$ -
It would be great to find another differential operator, let's call it
, such that , since in that case we would have the PDE $$\mathcal E(\Psi)=-\frac{\hbar^2}{2m} \nabla^2 (\Psi),$$due to the classical fact that for the free particle case we have . -
Unfortunately, when trying to extract the energy from
we are led to the expression $$\frac{\hbar \partial}{\partial t} \Psi=E A\cos(\frac{E}{\hbar}t)\sin(\frac{p}{\hbar}x).$$ But we can apply twice, so $$-\frac{\hbar^2 \partial^2}{\partial t^2} \Psi=E^2 \Psi,$$and then $$\left(\frac{\hbar^2 \partial^2}{\partial t^2} +E^2 \right)\Psi=0$$ -
But, if we admit complex numbers, we can consider the decomposition $$\frac{\hbar^2 \partial^2}{\partial t^2} +E^2 =\left(\frac{\hbar \partial}{\partial t} -iE\right)\left(\frac{\hbar \partial}{\partial t} +iE\right).$$
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Since
, we can consider another kind of waves, vibrating in a complex internal space, and defined by $$\tilde \Psi:=\left(\frac{\hbar \partial}{\partial t} -iE\right) \Psi=\cdots=\tilde A e^{-i\frac{E}{\hbar}t} \sin(\frac{p}{\hbar}x).$$ This expression is still a wave, and moreover, it satisfies: $$ \left(\frac{\hbar \partial}{\partial t} +iE\right) \tilde \Psi=0,$$ i.e., $$i\hbar \frac{\partial \tilde \Psi}{\partial t}=E\tilde \Psi.$$ -
So this is it, by renaming
as we have: $$i\hbar \frac{\partial \Psi}{\partial t} = -\frac{\hbar^2}{2m} \nabla^2 \Psi.$$
In conclusion, particles of energyand momentum have associated a wave of the form
and satisfying the PDE above, which was called Schrodinger equation.
Schrödinger was heavily inspired by an analogy with optics. He knew that classical mechanics (like