Keep an eye: I think there are two versions of Maurer-Cartan form: for Lie groups and for principal bundles. Probably they can be seen like the same, considering the Lie group as a principal bundle over a point...
Maurer-Cartan form of a Lie group
Given a Lie group with Lie algebra, we call (left-invariant) Maurer-Cartan form to the map:
for every , and where denote the left-multiplication by . It is a -valued 1-form: . Its meaning is that identifies every with (via left invariants vector fields), and so does with every two and At this way, we have a sense of parallel transport.
Another point of view for Maurer-Cartan form:
Given a basis for we can extend it to a global frame of by means of left translations (see examples here). Now, given , the components of in this frame are the Maurer-Cartan forms respect to the chosen basis. And the vector is also called the result of the Maurer-Cartan form. The individual Maurer-Cartan forms depend on the basis, but the "joint" one don't!
What is the relation between left and right actions and the Maurer-Cartan form?
Suppose an element . For a vector we have two vectors in : the left translated and the right translated .
Since is a vector space isomorphism, we can wonder what vector in corresponds to be means of it, i.e., the vector such that:
Suppose is a -principal bundle. Then, given we can consider the fundamental vector field. For , is a vertical vector since the action of leaves the fibres invariant. So for every we have a linear isomorphism (need to be proven)
The inverse , is like a Maurer-Cartan form, which acts only on vertical vector fields. That is, we can define a kind of -valued 1-form by
(By the way, I think that giving a connection to is "the same as" extending this 1-form to any vector, not only the vertical ones. In the case of a Cartan connection we are doing the same, but the values are taken in an extended Lie algebra...)