Connection form for LV in R3

What follows could be done more "abstractly", like in the note Euclidean plane, I think.

With the standard coordinate frame

Consider the Levi-Civita connection in R3, ∇. If we use the standard coordinates (x,y,z) we have the orthonormal frame {∂1,∂2,∂3} and we know that

∇∂i∂j=0

so in this case the connection form (Christoffel symbols, indeed) is Θ=0.

This can be deduced also with the Cartan's first structural equation. We have the coframe {dx,dy,dz} and since they are all closed

0=d(dx)=dx∧Θ11+dy∧Θ21+dz∧Θ310=d(dy)=dx∧Θ12+dy∧Θ22+dz∧Θ320=d(dz)=dx∧Θ13+dy∧Θ23+dz∧Θ33

Moreover, since the connection is metric and the frame is orthonormal we have that Θij=−Θji (see here) and, since is torsion free, ∂i⌟Θjk−∂j⌟Θik=−Tijk=0 (see here). Then

0=dy∧Θ21+dz∧Θ310=−dx∧Θ21+dz∧Θ320=−dx∧Θ31−dy∧Θ32

Observe, first,

∂1⌟Θ21=∂2⌟Θ11=0

Now, contracting ∂2 in the second equation

0=dx∧∂2⌟Θ21−dz∧∂2⌟Θ32

and from here ∂2⌟Θ21=0.
So Θ21 is a multiple of dz. For the same reasons, Θ31 is a multiple of dy and Θ32 is a multiple of dx.

Therefore

0=dy∧K12dz+dz∧K13dy0=−dx∧K12dz+dz∧K23dx0=−dx∧K12dy−dy∧K23dx

and K13=K12=−K23=−K12 and therefore all of them are 0.

With a general orthonormal frame

Consider now an orthonormal frame {e1,e2,e3} with dual coframe {ω1,ω2,ω3}. The connection form is, as usual, a matrix of 1-form Θ such that

∇e1=−Θ21e2−Θ31e3∇e2=Θ21e1+−Θ32e3∇e3=Θ31e1+Θ32e2

where we have used that since the connection is metric and the frame is orthonormal we have that Θij=−Θji (see here).

We have two pieces of data: the connection and the frame. And we can get Θ from them.